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Perkin Transactions 1 1972-2002 logo

Year 1978
Main Index

Issue 1


Contents pages

pg P001; DOI:
10.1039/P197800FP001
PDF
Enamines. Part 40. Carbon-13 nuclear magnetic resonance spectroscopy in the determination of aliphatic enamine configurations
Riccardo Stradi Pasqualina Trimarco and Aristide Vigevani
pg 1; DOI:
10.1039/P19780000001
PDF
Reactions of steroid allylic systems: solvolyses of cholest-4-en-3- and 3-yl trifluoroacetates
Giorgio Ortar Mario Paglialunga Paradisi Enrico Morera and Aurelio Romeo
pg 4; DOI:
10.1039/P19780000004
PDF
Asymmetric induction in the Darzens reaction by means of chiral phase-transfer in a two-phase system. The effect of binding the catalyst to a solid polymeric support
Stefano Colonna Roberto Fornasier and Ugo Pfeiffer
pg 8; DOI:
10.1039/P19780000008
PDF
The reaction of ketoximes with isothiocyanates
Robert F. Hudson and Hushang Dj-Forudian
pg 12; DOI:
10.1039/P19780000012
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Steroid analogues. Part 1. Preparation of intermediates containing rings C and D
David J. Humphreys Christopher E. Newall Howard A. Paskins and Gordon H. Phillipps
pg 15; DOI:
10.1039/P19780000015
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Steroid analogues. Part 2. Synthesis of unsymmetrical bi(cycloalkylidene)s via vic-dinitro-compounds
David J. Humphreys (Mrs.) Pamela M. Lawrence and Christopher E. Newall
pg 19; DOI:
10.1039/P19780000019
PDF
Steroid analogues. Part 3. Preparation of 4-cyclohexylidenecyclohex-2-enones and 6,7-dinor-5,8-secoestra-4,9-dien-3-ones by Birch reduction of 1-p-methoxyphenylcycloalkanols
David J. Humphreys (Mrs.) Pamela M. Lawrence Christopher E. Newall Gordon H. Phillipps and Peter A. Wall
pg 24; DOI:
10.1039/P19780000024
PDF
Steroid analogues. Part 4. Synthesis of 9-6,7-dinor-5,8-seco-steroids via-lactones
David J. Humphreys and Christopher E. Newall
pg 33; DOI:
10.1039/P19780000033
PDF
Steroid analogues. Part 5. Synthesis of 9-6,7-dinor-5,8-seco-steroids via3-1,3,4-thiadiazolines
David J. Humphreys Christopher E. Newall Gordon H. Phillipps and Gerald A. Smith
pg 45; DOI:
10.1039/P19780000045
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Thio-sugars. Part 2. Glycosides from acid-catalysed reactions of 1-O-acetyl-2,3-di-O-acyl-4-thiotetrofuranoses
Joan E. McCormick and R. Stanley McElhinney
pg 64; DOI:
10.1039/P19780000064
PDF
Structural investigation of lac resin. Part 13. Stereochemistry of some derivatives of shellolic acid, and of its 2-, 10-, and 2,10-epimers
Gobiehettipalayam B. Venkatasubramanian Krishnarajanagar N. Ganesh Virender S. Chauhan and Vijay K. Mahajan
pg 70; DOI:
10.1039/P19780000070
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Unsaturated steroids. Part 8. Synthesis of ergosta-5,7-diene-1,3-diol, the 4,4-dimethyl analogue, and 4,4-dimethylergosta-5,7-dien-3-ol
Riaz Ahmad David Hands Sai L. Leung John M. Midgley Hany Safwat and W. Basil Whalley
pg 74; DOI:
10.1039/P19780000074
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Unsaturated steroids. Part 9. Synthesis of some aromatic ring c steroids
Richard Edmunds John M. Midgley Linda G. Tagg Brian J. Wilkins and W. Basil Whalley
pg 76; DOI:
10.1039/P19780000076
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The chemistry of fungi. Part 74. Synthesis of ()-5-butyl-6,8-dihydroxy-3-pentyl-3,4-dihydroisocoumarin
Sheikh M. Afzal Richard Pike Nasim H. Rama Ian R. Smith Eric S. Turner and W. Basil Whalley
pg 81; DOI:
10.1039/P19780000081
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The chemistry of fungi. Part 75. A partial elaboration of the rosane system from podocarpic acid
C. George de Grazia and W. Basil Whalley
pg 84; DOI:
10.1039/P19780000084
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The chemistry of the insoluble red woods. Part 13. Synthesis of 2-(flavan-3-yl)isoflav-3-enes and of 6-benzyl-5-phenylbenzo[a]xanthens
James O. Oluwadiya and W. Basil Whalley
pg 88; DOI:
10.1039/P19780000088
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Issue 2


Contents pages

pg P005; DOI:
10.1039/P197800FP005
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X-Ray structure analysis of the tosylate ester of (1S,5S)-6,6-dimethyl-2-[(2S)-3,3,3-trichloro-2-hydroxypropyl]bicyclo[3.1.1]hept-2-ene, the major product of the iron(III) chloride-catalysed ene addition of chloral to (—)-(1S,5S)-pin-2(10)-ene
Michael J. Begley G. Bryon Gill and Brian Wallace
pg 93; DOI:
10.1039/P19780000093
PDF
Ring strain and the reactivity of dibenzophospholes and their quaternary salts: crystal and molecular structure of 5-(p-bromobenzyl)-5-phenyldibenzophospholium bromide
David W. Allen Ian W. Nowell A. Christopher Oades and Philip E. Walker
pg 98; DOI:
10.1039/P19780000098
PDF
Biosynthesis of the necic acids of the pyrrolizidine alkaloids. Further investigations of the formation of senecic and isatinecic acids in Senecio species
Nicholas M. Bale Rosalind Cahill Noel M. Davies Michael B. Mitchell Edward H. Smith and David H. G. Crout
pg 101; DOI:
10.1039/P19780000101
PDF
Tetracyclic triterpene synthesis. Part 1. Stereospecific conversion of 6-methoxy-1-tetralone into 7-methoxy-trans-3a,9b-dimethyl-1,3,3a,4,5-9b-hexahydrobenz[e]inden-2-one
Richard A. Packer and J. Stanley Whitehurst
pg 110; DOI:
10.1039/P19780000110
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Tetracyclic triterpene synthesis. Part 2. Deduction of ring fusion configurations in cis- and trans-7-methoxy-3a,9b-dimethyl-1,3,3a,4,5,9b-hexahydrobenz[e]inden-2-ones by nuclear magnetic resonance spectroscopy
Keith G. Orrell Richard A. Packer Vladimir ik and J. Stanley Whitehurst
pg 117; DOI:
10.1039/P19780000117
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Biosynthesis of the bisbenzylisoquinoline alkaloid cocsulin
Dewan S. Bhakuni Virender M. Labroo Awadhesh N. Singh and Randhir S. Kapil
pg 121; DOI:
10.1039/P19780000121
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Reactions of enol acetates with thallium(I) acetate–iodine
Richard C. Cambie Rodney C. Hayward Jeffrey L. Jurlina Peter S. Rutledge and Paul D. Woodgate
pg 126; DOI:
10.1039/P19780000126
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Reaction between 2,3,5-tri-O-acetyladenosine and aryl chloroformates. 2,3,5-Tri-O-acetyl-N(6)-phenoxycarbonyladenosine as an intermediate in the synthesis of 6-ureidopurine ribosides
P. Anne Lyon and Colin B. Reese
pg 131; DOI:
10.1039/P19780000131
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Structure and synthesis of some complex pyranoisoflavonoids from the bark of Dalbergia nitidula Welw. ex Bak.
Fanie R. van Heerden E. Vincent Brandt and David G. Roux
pg 137; DOI:
10.1039/P19780000137
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Tetracycline studies. Part 6. 6- and 12a-Hydroxylation of 6-methylpretetramid
Cedric H. Hassall and Gareth J. Thomas
pg 145; DOI:
10.1039/P19780000145
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Biosynthesis of flavoglaucin. Stereochemistry of aromatic isoprenylation
Janet K. Allen Kevin D. Barrow Alan J. Jones and Peter Hanisch
pg 152; DOI:
10.1039/P19780000152
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The chemistry of terpenes. Part 23. Reaction of (+)-carane-3,4-diol with sulphuric acid
Wesley Cocker and David H. Grayson
pg 155; DOI:
10.1039/P19780000155
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The chemistry of terpenes. Part 24. Some oxidation products of 1,5,5,6-tetramethylcyclohexa-1,3-diene (-pyronene)
Wesley Cocker Kevin J. Crowley and Krishnaswamy Srinivasan
pg 159; DOI:
10.1039/P19780000159
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18-Norpregna-8,11,13-trienes. Part 2. Preparation from 17-methyl-17-pregn-13-enes
Alex. C. Campbell Maurice S. Maidment John H. Pick Donald F. M. Stevenson and Gilbert F. Woods
pg 163; DOI:
10.1039/P19780000163
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Metabolic products of Entomophthora virulenta
Norman Claydon and John Frederick Grove
pg 171; DOI:
10.1039/P19780000171
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D-Homo-steroids. Part 7. Further studies on the mechanism of D-homoannulation of 17-hydroxypregnan-20-ones with Lewis acids
David N. Kirk and Conor R. McHugh
pg 173; DOI:
10.1039/P19780000173
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Intramolecular cyclisation of 2-phenylethyl isocyanates
Roy V. Davies Brian Iddon Hans Suschitzky and Maurice W. Gittos
pg 180; DOI:
10.1039/P19780000180
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Issue 3


Contents pages

pg P007; DOI:
10.1039/P197800FP007
PDF
Conformations of penicillin G: crystal structure of procaine penicillin G monohydrate and a refinement of the structure of potassium penicillin G
David D. Dexter and James M. van der Veen
pg 185; DOI:
10.1039/P19780000185
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The photolysis of o-azidobenzoic acid derivatives: a practicable synthesis of 2-alkoxy-3-alkoxycarbonyl-3H-azepines
Roger Purvis Robert K. Smalley Winston A. Strachan and Hans Suschitzky
pg 191; DOI:
10.1039/P19780000191
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Studies of heterocyclic compounds. Part 23. Diazo-coupling–deformylation of 3,4-dialkyl-1-aryl-6-oxa-6a4-thia-1,2-diazapentalenes: synthesis of 3,4-dialkyl-1,6-diaryl-6a4-thia-1,2,5,6-tetra-azapentalenes
Robert M. Christie David H. Reid Robert Walker and Robert G. Webster
pg 195; DOI:
10.1039/P19780000195
PDF
Reactions of fluoroalkyl radicals generated electrochemically. Part 1. Additions of trifluoromethyl radicals to olefinic and acetylenic bonds
Christopher J. Brookes Paul L. Coe Alan E. Pedler and John Colin Tatlow
pg 202; DOI:
10.1039/P19780000202
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Tautomerism of the enedione system of 15-oxoprostaglandin D2
Robert L. Jones and Norman H. Wilson
pg 209; DOI:
10.1039/P19780000209
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Reactions of the -carbanion species of (phenylthio)acetic acid and its ester with carbonyl compounds
Shûichi Yamagiwa Nobuto Hoshi Hitoshi Sato Hiroshi Kosugi and Hisachi Uda
pg 214; DOI:
10.1039/P19780000214
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Conformational aspects of some ring A-acetoxy-ketones in the cholestane series
Anchel Schwartz and Erwin Glotter
pg 224; DOI:
10.1039/P19780000224
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The acid-catalysed lactonisation of the norborn-5-en-2-ylacetic acids
David I. Davies and Michael D. Dowle
pg 227; DOI:
10.1039/P19780000227
PDF
Photoaddition of ethylenes and acetylenes to hexafluorobenzene
Derek Bryce-Smith Andrew Gilbert Brian H. Orger and Peter J. Twitchett
pg 232; DOI:
10.1039/P19780000232
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Dynamic stereochemistry of imines and derivatives. Part 13. The stereochemistry of the products from peroxyacid oxidation of bis-N-alkylaldimines
Derek R. Boyd Lionel C. Waring and W. Brian Jennings
pg 243; DOI:
10.1039/P19780000243
PDF
Asymmetric selection via addition. Optically active allenic sulphones
Mauro Cinquini Stefano Colonna and Franco Cozzi
pg 247; DOI:
10.1039/P19780000247
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Synthesis of N-acetyl derivatives of 17-(2-amino-oxazol-4-yl)-steroids and revised structure of N-acetylated 4- or 4,5-disubstituted 2-amino-oxazoles
Gianfranco Rapi Mauro Ginanneschi Mario Chelli and Andrea Boicelli
pg 249; DOI:
10.1039/P19780000249
PDF
Conformational studies. Part 9. Some exceptions to the axial halogeno-ketone rule
John S. E. Holker W. Reginald Jones Michael G. R. Leeming Gerald M. Holder John M. Midgley John E. Parkin and W. Basil Whalley
pg 253; DOI:
10.1039/P19780000253
PDF
Synthesis of hapten–polypeptide conjugates as antigen models for the N-terminal region of the -2-chain of rabbit skin collagen
Kiyoshi Nokihara and Heinz Berndt
pg 260; DOI:
10.1039/P19780000260
PDF
Abnormal elimination reactions of 3,17-diacetoxy-5,6-epoxyandrostan-7-ol
James R. Hanson Alan W. Johnson and Maria A. C. Kaplan
pg 263; DOI:
10.1039/P19780000263
PDF
Biosynthesis of the morphinandienone alkaloid, sebiferine
Dewan S. Bhakuni Virendra K. Mangla Awadhesh N. Singh and Randhir S. Kapil
pg 267; DOI:
10.1039/P19780000267
PDF
Reactions of diastereomeric 2,4,5-triphenyl-1,3-dioxolans with N-bromosuccinimide and t-butyl perbenzoate
Hiok-Huang Lee and Seong-Fong Chen
pg 270; DOI:
10.1039/P19780000270
PDF
The S-alkylation of sulphides by an activated carbohydrate epimine under acidic catalysis: the formation of -acetamido-sulphides. Part 2. Reactions with cyclic sulphides and with sulphides bearing an additional nucleophilic sulphur substituent
Brian Bannister
pg 274; DOI:
10.1039/P19780000274
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Synthesis of hydroxydihydroeremophilone
A. Reginald Pinder and W. Daniel Saunders
pg 282; DOI:
10.1039/P19780000282
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Tetranortriterpenoids and related substances. Part 20. New tetranortriterpenoids from the seeds of Chukrasia tabularis(Meliaceae); simple esters of phragmalin and 12-acetoxyphragmalin
Joseph D. Connolly Cecilia Labbé and David S. Rycroft
pg 285; DOI:
10.1039/P19780000285
PDF
Reductive dimerization of (+)-(R)-pulegone. Part 10. Absolute configuration of the spiro-atom of the resulting hydroxyperhydroindene-1-spirocyclohexanones
Ernest Forné and Josep Pascual
pg 288; DOI:
10.1039/P19780000288
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-Thioxo-esters. Part III. The spontaneous intramolecular cyclization of tautomeric diethyl thioacetylsuccinate. Preparation and tautomerism of 4-ethoxycarbonyl-5-methylthiophen-2(3H)-one
Fritz Duus
pg 292; DOI:
10.1039/P19780000292
PDF
The relative nucleophilicities of fluoride and aryloxy ions towards acyl and nitroaryl groups
Maria J. V. de Oliveira Baptista and David A. Widdowson
pg 295; DOI:
10.1039/P19780000295
PDF
Photochemical reactions of primary amines on nitrophenazines
Angelo Albini Gian Franco Bettinetti Elisa Fasani and Giovanna Minoli
pg 299; DOI:
10.1039/P19780000299
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Synthesis of ()-10,10-dimethylprostaglandin E1 methyl ester and its 15-epimer
Otto G. Plantema Henk de Koning and Henderikus O. Huisman
pg 304; DOI:
10.1039/P19780000304
PDF

Issue 4


Contents pages

pg P009; DOI:
10.1039/P197800FP009
PDF
N-halogenoamidines. Part 1. Amino-imidazolines and -imidazoles from N-chloro-N-arylamidines and enamines
Luisa Citerio Donato Pocar Riccardo Stradi and Bruno Gioia
pg 309; DOI:
10.1039/P19780000309
PDF
Iodine-catalysed stereomutation of chiral 1,4-dialkylbutadienes
Giampaolo Giacomelli Luciano Lardicci and Augusto Saba
pg 314; DOI:
10.1039/P19780000314
PDF
Selective reactions using metal phenoxides. Part 1. Reactions with formaldehyde
Giovanni Casiraghi Giuseppe Casnati Mara Cornia Andrea Pochini Giuseppe Puglia Giovanni Sartori and Rocco Ungaro
pg 318; DOI:
10.1039/P19780000318
PDF
Selective reactions using metal phenoxides. Part 2. Reactions with aromatic alcohols
Giovanni Casiraghi Giuseppe Casnati Mara Cornia Andrea Pochini Giovanni Sartori and Rocco Ungaro
pg 322; DOI:
10.1039/P19780000322
PDF
Thermolysis of some 4- and 5-substituted isothiazoles in the gas phase
Guillermo E. Castillo and Héctor E. Bertorello
pg 325; DOI:
10.1039/P19780000325
PDF
Epoxidation of lanost-9(11)-enes. The effect of a -carbonyl group upon the stereochemistry of epoxidation
Zdzisaw Paryzek
pg 329; DOI:
10.1039/P19780000329
PDF
Microbial transformation of -sitosterol: accumulation of 3-(5-hydroxy-7a-methyl-1-oxo-3aH-hexahydroindan-4-yl)propionic acid and the X-ray structural identification of its -lactone
Ulrike Schömer William S. Sheldrick and Fritz Wagner
pg 336; DOI:
10.1039/P19780000336
PDF
Enamine chemistry. Part 24. 2,2-versus 2,6-Disubstitution in 2-alkylcyclohexanone enamines. Factors affecting the regioselectivity and stereoselectivity of enamine alkylation and protonation
Peter W. Hickmott and Nicholas F. Firrell
pg 340; DOI:
10.1039/P19780000340
PDF
Further synthetic approaches to flavines (isoalloxazines). A new synthesis of riboflavine
Fumio Yoneda Yoshiharu Sakuma and Kazuo Shinomura
pg 348; DOI:
10.1039/P19780000348
PDF
Studies on keten and its derivatives. Part 86. Photoreaction of diketen with dimedone and isophorone
Tetsuzo Kato Masayuki Sato and Yoshinori Kitagawa
pg 352; DOI:
10.1039/P19780000352
PDF
Two new diterpenoids from Teucrium fruticans
Giuseppe Savona Salvatore Passannanti M. Pia Paternostro Franco Piozzi James R. Hanson Peter B. Hitchcock and Michael Siverns
pg 356; DOI:
10.1039/P19780000356
PDF
Flavone and triterpenoid constituents of Elaegia utilis
Tesfaye Biftu and Robert Stevenson
pg 360; DOI:
10.1039/P19780000360
PDF
Heterocyclic polyfluoro-compounds. Part 25. The photochemical addition of ethylene to pentafluoropyridine: formation of 1 : 1- and 2 : 1-adducts
Michael G. Barlow David E. Brown and Robert N. Haszeldine
pg 363; DOI:
10.1039/P19780000363
PDF
Some reactions of meso-formyloctaethylporhyrin
Dennis P. Arnold Alan W. Johnson and Mailvaganam Mahendran
pg 366; DOI:
10.1039/P19780000366
PDF
Asymmetric induction in the borohydride reduction of carbonyl compounds by means of chiral phase-transfer catalysts. Part 2
Stefano Colonna and Roberto Fornasier
pg 371; DOI:
10.1039/P19780000371
PDF
Reactions of fatty acids with amines. Part 2. Sequential thermal reactions of stearic (octadecanoic) acid with some 1,2- and 1,3-aminoalcohols and bis-amines
Richard N. Butler Cornelius B. O'Regan and Patrick Moynihan
pg 373; DOI:
10.1039/P19780000373
PDF
Heterocyclic polyfluoro-compounds. Part 26. Synthesis of 3,6-bis-trifluoromethyl-pyridazines and -dihydropyridazines
Michael G. Barlow Robert N. Haszeldine and John A. Pickett
pg 378; DOI:
10.1039/P19780000378
PDF
Biosynthesis of cocsulinin
Dewan S. Bhakuni Sudha Jain and Awadhesh N. Singh
pg 380; DOI:
10.1039/P19780000380
PDF
Terpenoids and related compounds. Part 24. Molecular rearrangements in friedo-oleanenes
Pasupati Sengupta (Miss) Manju Sen and (Miss) Usha Sarkar
pg 384; DOI:
10.1039/P19780000384
PDF
Calciferol and its relatives. Part 21. A synthesis of (S)-(Z)-2-(5-hydroxy-2-methylenecyclohexylidene)ethanol
Basil Lythgoe Robert Manwaring John R. Milner Thomas A. Moran Mayara E. N. Nambudiry and John Tideswell
pg 387; DOI:
10.1039/P19780000387
PDF
Depsidone synthesis. Part 11. Synthesis of some fungal depsidones related to nidulin
Peter Djura and Melvyn V. Sargent
pg 395; DOI:
10.1039/P19780000395
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Issue 5


Contents pages

pg P011; DOI:
10.1039/P197800FP011
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The reactions of 2,4-dinitrobenzenediazonium ions with furans
Michael G. Bartle Suresh T. Gore Raymond K. Mackie Sushila Mhatre and John M. Tedder
pg 401; DOI:
10.1039/P19780000401
PDF
Synthesis of the isomeric dinitro-p-phenylenediamines by nitration of NN-bis(phenylsulphonyl)-p-phenylenediamine
Kwong-Yung Chu and John Griffiths
pg 406; DOI:
10.1039/P19780000406
PDF
Neighbouring group effects in the addition of hypobromous acid to unsaturated steroids
Erwin Glotter and Pnina Krinsky
pg 408; DOI:
10.1039/P19780000408
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Neighbouring group effects in the acid-catalysed opening of steroidal epoxides
Erwin Glotter and Pnina Krinsky
pg 413; DOI:
10.1039/P19780000413
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Anomalous halogenation of N-(2-acetylbenzofuran-3-yl)acetamide
Steven Jordan and Roger E. Markwell
pg 419; DOI:
10.1039/P19780000419
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Polyhalogenoallenes. Part 11. The preparation of some new perfluoro-1,2-dienes and their reactions with nucleophiles
Paul W. L. Bosbury Roy Fields and Robert N. Haszeldine
pg 422; DOI:
10.1039/P19780000422
PDF
1,2,3-Triazoles. Part 3. 4-Aminotriazole-5-carbaldehydes from 4-aminotriazoles
Adrien Albert and Clara J. Lin
pg 427; DOI:
10.1039/P19780000427
PDF
Studies on heterocyclic analogues of azulene. Part 2. Cycloaddition reactions of aza-analogues of azulene with dimethyl acetylenedicarboxylate: intermediacy of a 1,8-dipolar species
Noritaka Abe Yasuko Tanaka and Tarozaemon Nishiwaki
pg 429; DOI:
10.1039/P19780000429
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Diarylmethane formation in the reaction of various metal acetates with alkylbenzenes in the presence of perchloric acid
Sakuya Tanaka Sakae Uemura and Masaya Okano
pg 431; DOI:
10.1039/P19780000431
PDF
Synthesis of C-homoerysodienone and its conversion into B-homoerysodienone via a dibenz[d,f]azecine; potential precursors of the homoerythrina alkaloids
Edward McDonald and Apichart Suksamrarn
pg 434; DOI:
10.1039/P19780000434
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Design of the substrate for oxidative phenol coupling. An efficient synthesis of the C-homoerythrinan skeleton
Edward McDonald and Apichart Suksamrarn
pg 440; DOI:
10.1039/P19780000440
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Novel aspects in the reaction of 2-diazo-2-(phenylthio)acetophenone with arenesulphenyl chlorides: formation of -ketoaldehyde thioacetal chlorides via cyclic sulphonium -(arylthio)phenacylides
William T. Flowers Geoffrey Holt and Patrick P. McCleery
pg 446; DOI:
10.1039/P19780000446
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Synthesis of bridged macrocyclic polyethers of high complexing ability with group 1a salts
David G. Parsons
pg 451; DOI:
10.1039/P19780000451
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Horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide
Guido Galliani Bruno Rindone and Augusto Marchesini
pg 456; DOI:
10.1039/P19780000456
PDF
Studies on the syntheses of heterocyclic compounds. Part 738. Photo-oxygenation of 9-oxo-9H-pyrrolo[1,2-a]indoles
Tetsuji Kametani Tatsushi Ohsawa Masataka Ihara and Keiichiro Fukumoto
pg 460; DOI:
10.1039/P19780000460
PDF
Stereoselective reductions and alcohol deoxygenation by a phosphine in the 5,10-dihydrodibenzo[b,e]phosphorin series
Itshak Granoth Yoffi Sagall and Haim Leader
pg 465; DOI:
10.1039/P19780000465
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General synthesis of dibenzotetrathiafulvalenes
Jyuzo Nakayama Etsuro Seki and Masamatsu Hoshino
pg 468; DOI:
10.1039/P19780000468
PDF
A novel aromatisation reaction of 11-oxolanostanes
William Lawrie William Hamilton John McLean and James Meney
pg 471; DOI:
10.1039/P19780000471
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Reactions of -dodecatrienediylnickel with dimethyl acetylenedicarboxylate and methyl propiolate
Raymond Baker Peter C. Bevan Richard C. Cookson Alison H. Copeland and Andrew D. Gribble
pg 480; DOI:
10.1039/P19780000480
PDF
New routes for the synthesis of pyrrolo-[3,2-d]- and -[2,3-d]-pyrimidine systems starting from a common pyrrole derivative
M. Teresa Garcia-Lòpez Federico G. de las Heras and Manfred Stud
pg 483; DOI:
10.1039/P19780000483
PDF
Reaction of some triarylmethyl radicals, polyarylalkenes, and 9,10-dihydro-9,10-epidioxyanthracenes with sulphur dioxide; detection of radicals and/or cations derived from the corresponding cation radicals
Masatomo Nojima Masato Takagi Minoru Morinaga Gensai Nagao and Niichiro Tokura
pg 488; DOI:
10.1039/P19780000488
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Organoiron complexes in organic synthesis. Part 2. Conformational and steric effects of methyl substituents in tricarbonyliron derivatives of bicyclo[4.4.0]decadienes
Anthony J. Pearson
pg 495; DOI:
10.1039/P19780000495
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Thio-sugars. Part 3. 4-Thiotetrofuranose nucleosides
Joan E. McCormick and R. Stanley McElhinney
pg 500; DOI:
10.1039/P19780000500
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Applications of high-potential quinones. Part 12. Studies on an organic reaction cycle for the production of hydrogen from water
Colin M. Tice and Alan B. Turner
pg 505; DOI:
10.1039/P19780000505
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Issue 6


Contents pages

pg P013; DOI:
10.1039/P197800FP013
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Relative abundance of racemic and meso-diastereoisomers of 3,3-diphenylbiphthalid-3-yl arising from the corresponding chemically and photochemically generated free radicals
Michel Pfau Francis Gobert Jean-Claude Gramain and Marie-France Lhomme
pg 509; DOI:
10.1039/P19780000509
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v-Triazolo[5,4-d]pyrimidines (8-azapurines). Part 20. 1-Alkyl derivatives
Adrien Albert
pg 513; DOI:
10.1039/P19780000513
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8-Quinolyl esters of nucleoside 5-phosphates. Part 2. Application to the synthesis of oligodeoxyribonucleotides bearing a 5-phosphate end group
Hiroshi Takaku Ryuichi Yamaguchi and Tsujiaki Hata
pg 519; DOI:
10.1039/P19780000519
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Oxymetallation. Part 11. Synthesis of cyclic secondary alkyl peroxides via the peroxymercuration of ,-dienes
A. J. Bloodworth and M. E. Loveitt
pg 522; DOI:
10.1039/P19780000522
PDF
Stereochemistry of the oxymercuration of substituted methylenecyclohexanes and methylenecyclopentanes
Yasuhisa Senda Shin-ichi Kamiyama and Shin Imaizumi
pg 530; DOI:
10.1039/P19780000530
PDF
Extractives from guttiferae. Part 34. Kolaflavanone, a new biflavanone from the nuts of Garcinia kola Heckel. Applications of 13C nuclear magnetic resonance in elucidation of the structures of flavonoids
Philip J. Cotterill Feodor Scheinmann and Ian A. Stenhouse
pg 532; DOI:
10.1039/P19780000532
PDF
Some 1H-4,1,2-benzothiadiazines and 1H-4,1,2-benzothiadiazine 4,4-dioxides
Donald E. Ames Sosale Chandrasekhar and Kristian J. Hansen
pg 539; DOI:
10.1039/P19780000539
PDF
Reaction of phenylhydrazones with bis(-allyl)-nickel and -palladium complexes
Raymond Baker Malcolm S. Nobbs and David T. Robinson
pg 543; DOI:
10.1039/P19780000543
PDF
Keten SS-acetals. Part 9. Reaction of -oxo- and -cyano-keten SS-acetals with cyanoacetamide: a new general method for substituted and fused 4-alkylthio-3-cyano-2(1H)-pyridones and formation of novel pyridones through base-induced rearrangements
R. R. Rastogi A. Kumar H. Ila and H. Junjappa
pg 549; DOI:
10.1039/P19780000549
PDF
Keten SS-acetals. Part 10. Reaction of -oxoketen SS-acetals with N-alkylcyanoacetamides: a new general method for substituted and fused 2,7-dialkyl-8-amino-5-cyano-2,7-naphthyridine-1,6(2H,7H)-diones
R. R. Rastogi A. Kumar H. Ila and H. Junjappa
pg 554; DOI:
10.1039/P19780000554
PDF
Addition reaction of 2-iminocyclopentanedithiocarboxylic acid with Schiff's bases: a novel route to the synthesis of 1,3-thiazine derivatives
Naoaki Fukada Masahide Kato Hitoshi Seki Masayuki Kawana and Tatsuo Takeshima
pg 558; DOI:
10.1039/P19780000558
PDF
The chemistry of pseudomonic acid. Part 1. The absolute configuration of pseudomonic acid A
Roger G. Alexander J. Peter Clayton Kong Luk Norman H. Rogers and Trevor J. King
pg 561; DOI:
10.1039/P19780000561
PDF
Cleavage of the epoxide ring in trans-epoxy-alcohols by sodium borohydride in methanol
Martin Weissenberg Pnina Krinsky and Erwin Glotter
pg 565; DOI:
10.1039/P19780000565
PDF
Steric course of reduction with sodium borohydride of steroidal -epoxy-ketones
Martin Weissenberg and Erwin Glotter
pg 568; DOI:
10.1039/P19780000568
PDF
Overcrowded molecules. Part 14. Photochromic systems involving (Z)-1-methylpropylidene(diphenylmethylene)succinic and (E)-3,5-dimethoxybenzylidene(alkyl-substituted methylene)succinic anhydrides
Paul J. Darcy Robert J. Hart and Harry G. Heller
pg 571; DOI:
10.1039/P19780000571
PDF
Totally synthetic steroid heterocycles. Part 1. Synthesis of intermediate precursors of 16-oxa- and 16-thia-D-homoestrogens
Tadao Terasawa and Toshihiko Okada
pg 576; DOI:
10.1039/P19780000576
PDF
Oxidation of aromatic substrates. Part 3. Synthesis of amino-acids by the selective action of ruthenium tetraoxide upon arylalkylamines
David C. Ayres
pg 585; DOI:
10.1039/P19780000585
PDF
Oxidation of aromatic substrates. Part 4. Action of ruthenium tetraoxide on some substituted biphenyls
David C. Ayres and R. Gopalan
pg 588; DOI:
10.1039/P19780000588
PDF
Calciferol and its relatives. Part 22. A direct total synthesis of vitamin D2 and vitamin D3
Basil Lythgoe Thomas A. Moran Mayara E. N. Nambudiry John Tideswell and Paul W. Wright
pg 590; DOI:
10.1039/P19780000590
PDF
An alternative route to furanoid and pyranoid glycals
Stephen J. Eitelman Richard H. Hall and Amor Jordaan
pg 595; DOI:
10.1039/P19780000595
PDF
Cyclic mesoionic compounds. Part 14. The electric dipole moments of mesoionic heterocycles
Robert N. Hanley W. David Ollis Christopher A. Ramsden Geoffrey Rowlands and Leslie E. Sutton
pg 600; DOI:
10.1039/P19780000600
PDF
Asymmetric syntheses. Part 10. The synthesis and reduction of N-phenylazomethines with a lithium aluminium hydride–3-O-benzyl-1,2-O-cyclohexylidene--D-glucofuranose complex to give optically active secondary amines
Stephen R. Landor Olatunji O. Sonola and Austin R. Tatchell
pg 605; DOI:
10.1039/P19780000605
PDF
A route to 6-functionalised 1,3-diaza-azulenes and aminotropones via hydride replacement from cycloheptatrienones
Marino Cavazza Renzo Cabrino Francesco Del Cima and Francesco Pietra
pg 609; DOI:
10.1039/P19780000609
PDF
Photoinduced transformations. Part 38. Photoreactions of 17-ethoxycarbonylmethylene-etiojerva-5,13(17)- and -5,16-diene-3,11,20-triol 3,20-diacetate 11-nitrites
Hiroshi Suginome Sanji Sugiura Norihisa Yonekura Tadashi Masamune and Eiji Osawa
pg 612; DOI:
10.1039/P19780000612
PDF
Biosynthesis of the abnormal Erythrina alkaloids, cocculidine and cocculine
Dewan S. Bhakuni and Awadhesh N. Singh
pg 618; DOI:
10.1039/P19780000618
PDF
Biosynthesis of isocorydine (1,2,10-trimethoxy-6a-aporphin-11-ol)
Om Prakash Dewan S. Bhakuni and Randhir S. Kapil
pg 622; DOI:
10.1039/P19780000622
PDF
Olefin metathesis. Development of a new catalyst employing tungsten hexachloride and lithium aluminium hydride
Stephen A. Matlin and Peter G. Sammes
pg 624; DOI:
10.1039/P19780000624
PDF
Dimerisation of 3-aryl-2-cyanothioacrylamides. A [2s+ 4s] cyclo-addition to give substituted 3,4-dihydro-2H-thiopyrans
John S. A. Brunskill Asish De and David F. Ewing
pg 629; DOI:
10.1039/P19780000629
PDF
Sulphides, sulphoxides, and sulphones derived from salicyclic acids
George R. Brown Justus K. Landquist and David R. Summers
pg 633; DOI:
10.1039/P19780000633
PDF
Organometallic complexes in synthesis. Part 9. Tricarbonyliron derivatives of dihydroanisic esters
Arthur J. Birch and Anthony J. Pearson
pg 638; DOI:
10.1039/P19780000638
PDF
Salviarin, a new diterpenoid from Salvia splendens
Giuseppe Savona Maria Pia Paternostro Franco Piozzi James R. Hanson Peter B. Hitchcock and Sunday A. Thomas
pg 643; DOI:
10.1039/P19780000643
PDF
Intramolecular cyclisation of substituted phenoxyethanols and related compounds with mercury(II) oxide and iodine
André Goosen and Cedric W. McCleland
pg 646; DOI:
10.1039/P19780000646
PDF
N-Iodo-amides: cyclisation of substituted biphenyl-2-carboxamides
Stephen A. Glover and André Goosen
pg 653; DOI:
10.1039/P19780000653
PDF
Synthetic studies on the sesquiterpene antibiotic verrucarol
Ernest W. Colvin Swiatoslaw Malchenko Ralph A. Raphael and James S. Roberts
pg 658; DOI:
10.1039/P19780000658
PDF
Studies on the syntheses of heterocyclic compounds. Part 744. A synthesis of 1-benzazocin-5-ones from 2,3-dihydro-1H-pyrrolo[1,2-a]indoles; a synthetic approach to the mitomycins
Tetsuji Kametani Kimio Takahashi Masataka Ihara and Keiichiro Fukumoto
pg 662; DOI:
10.1039/P19780000662
PDF
The carbon-13 nuclear magnetic resonance spectra of isoflavones
Andrew Pelter Robert S. Ward and Robert J. Bass
pg 666; DOI:
10.1039/P19780000666
PDF
Studies related to penicillins. Part 17. Reactions of (2S)-3-mercapto-3-methyl-2-{(1S,5R)-7-oxo-4-oxa-2,6-diazabicyclo[3.2.0]hept-2-en-6-yl}-butanoates
Wasna Baker Chandra M. Pant and Richard J. Stoodley
pg 668; DOI:
10.1039/P19780000668
PDF
The chemistry of heteroarylphosphorus compounds. Part 11. The effects of 3-furyl and 3-thienyl substituents at phosphorus on the rate and course of alkaline hydrolysis of phosphonium salts and on the decomposition of phosphonium betaines
David W. Allen and Barrie G. Hutley
pg 675; DOI:
10.1039/P19780000675
PDF
Synthesis of -damascone [trans-1-(2,6,6-trimethylcyclohex-2-enyl)but-2-en-1-one] by a catalysed Diels–Alder reaction with inverse electron demand
Richard C. Cookson and Robert M. Tuddenham
pg 678; DOI:
10.1039/P19780000678
PDF

Issue 7


Contents pages

pg P015; DOI:
10.1039/P197800FP015
PDF
A novel synthesis of pyrazol-3-ones from biacetyl dimer and arenediazonium salts
Carlo Venturello
pg 681; DOI:
10.1039/P19780000681
PDF
Mechanism of the photorearrangements of phenylthiazoles
Minoru Maeda and Masaharu Kojima
pg 685; DOI:
10.1039/P19780000685
PDF
Reactions of nitroarenes with Grignard reagents. General method of synthesis of alkyl-nitroso-substituted bicyclic aromatic systems
Giuseppe Bartoli Rino Leardini Alessandro Medici and Goffredo Rosini
pg 692; DOI:
10.1039/P19780000692
PDF
Anodic oxidation of phenolic compounds. Part 5. Anodic methoxylation of phenols. A simple synthesis of quinones, quinone acetals, and 4-methyl--methoxycyclohexa-2,5-dienones
Anders Nilsson Ulf Palmquist Tore Pettersson and Alvin Ronlán
pg 696; DOI:
10.1039/P19780000696
PDF
Anodic functionalisation in synthesis. Part 1. Methoxylation of methyl-substituted benzene and anisole derivatives, and the synthesis of aromatic aldehydes by anodic oxidation
Anders Nilsson Ulf Palmquist Tore Pettersson and Alvin Ronlán
pg 708; DOI:
10.1039/P19780000708
PDF
Pyrimido[1,4]benzothiazines and pyrimido[1,5]benzothiazepines. Part 3. Novel ring-contraction and ring-opening of pyrimido[1,5]benzothiazepines
Tokiyuki Hiramitsu Yoshifumi Maki and Shigeo Senda
pg 716; DOI:
10.1039/P19780000716
PDF
Cyclisation of benzylaminoacetonitriles. Part 2. Evidence for two mechanisms of cyclisation
David N. Harcourt Norman Taylor and Roger D. Waigh
pg 722; DOI:
10.1039/P19780000722
PDF
Studies of the syntheses of heterocyclic compounds containing benzopyrone. Part 2. Syntheses of khellin analogues
Toshio Watanabe Sadamu Katayama Yoshihiko Nakashita and Masashige Yamauchi
pg 726; DOI:
10.1039/P19780000726
PDF
Steric course of cross coupling of organocopper reagents with allylic acetates
Pierre Crabbé Jean-Marie Dollat Josefina Gallina Jean-Louis Luche Esperanza Velarde Michael L. Maddox and Laszlo Tökès
pg 730; DOI:
10.1039/P19780000730
PDF
Dienone–phenol type rearrangements. Part 5. Confirmation of a rearrangement pathway using carbon-13 labelling
Brian R. Davis Gordon W. Rewcastle and Paul D. Woodgate
pg 735; DOI:
10.1039/P19780000735
PDF
Structure and synthesis of the phenanthrenes Tal and TaV from Tamus communis
Roy M. Letcher and Kum-Moon Wong
pg 739; DOI:
10.1039/P19780000739
PDF
Ring-contraction of 5,6-epoxyandrostane-4,17-dione
James R. Hanson David Raines and Harry Wadsworth
pg 743; DOI:
10.1039/P19780000743
PDF
Strong evidence for thiazirines as stable intermediates at cryogenic temperatures in the photolytic formation of nitrile sulphides from arylsubstituted 1,2,3,4-thiatriazole, thiatriazole 3-oxide, and 1,3,4-oxathiazol-2-one
Arne Holm Niels Harrit and Ib Trabjerg
pg 746; DOI:
10.1039/P19780000746
PDF
The constitution of (1R)-sequirin-D (Sequoia sempervirens), a biogenetically novel norlignan, by direct X-ray analysis
Michael J. Begley R. Vaughan Davies Peter Henley-Smith and Donald A. Whiting
pg 750; DOI:
10.1039/P19780000750
PDF
Cyclisation of phenolic oximes. Part 4. Cyclisation of 6-acetonyl-6-hydroxy-2,4-di-t-butylcyclohexa-2,4-dienone oxime with hydrogen chloride
Alexander R. Forrester Ronald H. Thomson and Soo On Woo
pg 755; DOI:
10.1039/P19780000755
PDF
Microbial transformations of natural antitumour agents. Part 5. The structure of a novel vindoline dimer produced by Streptomyces griseus
Thomas Nabih Leisa Youel and John P. Rosazza
pg 757; DOI:
10.1039/P19780000757
PDF
Action of trimethyl phosphate on ribonucleosides in aqueous solution
Kiyoshi Yamauchi and Masayoshi Kinoshita
pg 762; DOI:
10.1039/P19780000762
PDF
Bile pigment studies. Part 4. Some novel reactions of metalloporphyrins with thallium(III) and cerium(IV) salts. Ring cleavage of meso-tetraphenylporphyrin
Brian Evans Kevin M. Smith and José A. S. Cavaleiro
pg 768; DOI:
10.1039/P19780000768
PDF
Synthesis of (R)-[1-2H,1-3H]- and [1,1,10,10-2H4]-decane: inverse isotope effects in the protonation of anions from 1,3-dithians
Bernard T. Golding Panayiotis V. Ioannou and Ian F. Eckhard
pg 774; DOI:
10.1039/P19780000774
PDF
A new route to the rare tricyclo[3.3.1.02,7]nonane skeleton. Synthesis of 1,2,3,4,7-pentafluorotricyclo[3.3.1.02,7]non-3-ene-8,8-diol hemihydrate via thermolysis of pentafluorophenyl prop-2-enyl ether, and related studies
Gerald M. Brooke David H. Hall and Harrison M. M. Shearer
pg 780; DOI:
10.1039/P19780000780
PDF
Polymer modification and synthesis using sulphenyl derivatives. Part 8. Addition of arylsulphenyl chlorides to polyisoprene
Gavin M. Buchan and G. Gordon Cameron
pg 783; DOI:
10.1039/P19780000783
PDF

Issue 8


Contents pages

pg P017; DOI:
10.1039/P197800FP017
PDF
Deoxygenation reactions of as-triazine oxides: unusual reactivity of naphtho[1,2-e][1,2,4]triazin-2(3H)-one 1-oxides and the crystal and molecular structure of 3-methylnaphtho[1,2-e][1,2,4]triazin-2(3H)-one 1-oxide
Fergus J. Lalor Francis L. Scott George Ferguson and Wayne C. Marsh
pg 789; DOI:
10.1039/P19780000789
PDF
Nitrogen bridgehead compounds. Part 5. Cyclization of 2-(2-pyridylaminomethylene)-succinates and -glutarates
Lelle Vasvári-Debreczy István Hermecz Zoltán Mészáros Ágnes Horváth and Piroska Simon-Párkányi
pg 795; DOI:
10.1039/P19780000795
PDF
A model folate synthesis incorporating the basic picolyl ester group
Charles N. C. Drey and Gareth P. Priestley
pg 800; DOI:
10.1039/P19780000800
PDF
Reduction of 6-hydroxyimino-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane and nitrosation of the resulting amines. New rearrangement products of the monoterpenoid 1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane
Francesco Bondavalli Angelo Ranise Pietro Schenone and Silvia Lanteri
pg 804; DOI:
10.1039/P19780000804
PDF
Steroidal analogues of unnatural configuration. Part 12. Ring A reactions of 9-methyl-5,9,10- and 9-methyl-5,9,10-estran-3-ones: conformational analysis and X-ray crystallography of products
Jan C. A. Boeyens James R. Bull Jan Floor and Albert Tuinman
pg 808; DOI:
10.1039/P19780000808
PDF
Transformations of penicillins and cephalosporins: reactions of chlorosulphonyl isocyanate with penams, cephems, and azetidin-2-ones
Malcolm M. Campbell Robert G. Harcus and Kenneth H. Nelson
pg 817; DOI:
10.1039/P19780000817
PDF
Dithiols. Part 28. Conversion of 1,3-dithiolan-2-ones, 1,3-oxathiolan-2-ones, and 1,3-oxathiolan-2-thiones into 1,3-dithiolan-2-thiones
Richard C. Forster and Leonard N. Owen
pg 822; DOI:
10.1039/P19780000822
PDF
Scope and stereochemistry of an olefin synthesis from -hydroxysulphones
Philip J. Kocienski Basil Lythgoe and Steven Ruston
pg 829; DOI:
10.1039/P19780000829
PDF
Calciferol and its relatives. Part 23. An alternative synthesis of Windaus and Grundmann's C19 ketone
Philip J. Kocienski Basil Lythgoe and David A. Roberts
pg 834; DOI:
10.1039/P19780000834
PDF
Reactions of 5,6,7,8-tetrahalogeno-1,4-dihydronaphthalen-1,4-imines with dimethyl acetylenedicarboxylate
John M. Vernon Munir Ahmed and Larry J. Kricka
pg 837; DOI:
10.1039/P19780000837
PDF
A rapid and convenient synthesis of the sex pheromone of the Douglas fir lepidoptera Orgyia pseudotsugata
Marcel Fetizon and Catherine Lazare
pg 842; DOI:
10.1039/P19780000842
PDF
Pyrroles and related compounds. Part 39. Structural and biosynthetic studies of the Chlorobium chlorophylls-660 (bacteriochlorophylls c). Incorporations of methionine and porphobilinogen
George W. Kenner John Rimmer Kevin M. Smith and John F. Unsworth
pg 845; DOI:
10.1039/P19780000845
PDF
Intramolecular aromatic hydroxylation via irradiation of pyridine N-oxide derivatives
Peter G. Sammes Guido Serra-Errante and Alan C. Tinker
pg 853; DOI:
10.1039/P19780000853
PDF
Keten dithioacetals. Part 11. Reaction of 3-cyano-4-methylthio-2(1H)-pyridones with hydrazine and guanidine: synthesis of novel substituted and fused pyrazolo[4,3-c]pyridone and pyrido[4,3-d]pyrimidine derivatives
Arvind Kumar Hiriyakkanavar Ila and Hiriykkanavar Junjappa
pg 857; DOI:
10.1039/P19780000857
PDF
Azabenzocycloheptenones. Part 19. Formation of some heterocyclic annelated compounds from 1,2,3,4-tetrahydro-1-benzazepine derivatives
George R. Proctor and Brian M. L. Smith
pg 862; DOI:
10.1039/P19780000862
PDF
Synthesis of tetradehydrocorrins, corroles, and corrologens related to 12-decarboxyuroporphyrin III and uroporphyrin III
Jurgen Engel Albert Gossauer and Alan W. Johnson
pg 871; DOI:
10.1039/P19780000871
PDF
Synthesis of 9-oxoxanthen-2-carboxylic acids
Robert Graham and John R. Lewis
pg 876; DOI:
10.1039/P19780000876
PDF
Oxidations of some mono- and bis-(toluene-p-sulphonyl)hydrazones with mercury(II) and lead(IV) acetates: interception of hydrazonometallo intermediates. Reactions of mercury(II) acetate with nitrogen compounds. Part 2
Richard N. Butler Anne B. Hanahoe and W. B. King
pg 881; DOI:
10.1039/P19780000881
PDF
Triazines and related products. Part 21. Cyclisation of 3-amino-5-hydrazinopyrazole and 3-amino-5-hydrazino-1,2,4-triazole to azolo[5,1-c][1,2,4]triazines
Elizabeth Jane Gray Howard N. E. Stevens and Malcolm F. G. Stevens
pg 885; DOI:
10.1039/P19780000885
PDF
Preparation of a series of 3- and 6-substituted 1,2,3,4-tetra- and 1,2,3,4,4a,9a-hexa-hydrocarbazoles
James H. P. Utley and Samuel O. Yeboah
pg 888; DOI:
10.1039/P19780000888
PDF
Plant proanthocyanidins. Part 5. Sorghum polyphenols
Raj K. Gupta and Edwin Haslam
pg 892; DOI:
10.1039/P19780000892
PDF
Pyrrolizidine alkaloid analogues. Part 2. Further hydroxymethyl-1-methyl-3-pyrrolines (synthanecines), and the preparation and esterification of some hydroxymethylpyrroles
A. Robin Mattocks
pg 896; DOI:
10.1039/P19780000896
PDF
Reaction of benzophenone hydrazone with 1-chlorobenzotriazole
Martin Keating Michael J. Sasse and Richard C. Storr
pg 905; DOI:
10.1039/P19780000905
PDF
1-Bromo- and 1-iodo-benzotriazoles
Michael J. Sasse and Richard C. Storr
pg 909; DOI:
10.1039/P19780000909
PDF

Issue 9


Contents pages

pg P019; DOI:
10.1039/P197800FP019
PDF
New syntheses of thionitrites and their chemical reactivites
Shigeru Oae Yong H. Kim Daikichi Fukushima and Kichi Shinhama
pg 913; DOI:
10.1039/P19780000913
PDF
Ozonolysis of tetrahydrophthalimides (cyclohex-4-ene-1,2-dicarboximides): a sterically dependent unsymmetrical oxidative cleavage reaction
A. Harry Andrist and Mark J. Kovelan
pg 918; DOI:
10.1039/P19780000918
PDF
Photochemistry of quinoxaline 1-oxide and some of its derivatives
Angelo Albini Roberto Colombi and Giovanna Minoli
pg 924; DOI:
10.1039/P19780000924
PDF
The synthesis and oxidation of N-hydroxy-derivatives of the -adrenoceptor antagonists bufuralol and toliprolol
Steven Jordan Roger E. Markwell and Barbara S. Woolcott
pg 928; DOI:
10.1039/P19780000928
PDF
Acylation of pyran-2,4,6-trione (acetonedicarboxylic anhydride)
Erik G. Frandsen and Niels Jacobsen
pg 933; DOI:
10.1039/P19780000933
PDF
Heteroarene-fused benzodiazepines. Part 1. Synthesis of thieno-[2,3-b][1,5]-, -[3,2-b][1,5]-, and -[3,4-b][1,5]-benzodiazepinones
Jiban K. Chakrabarti Terence A. Hicks Terrence M. Hotten and David E. Tupper
pg 937; DOI:
10.1039/P19780000937
PDF
Hydrogen bonding in organic synthesis. Part 8. Reactions of 2-nitropropane in the presence of tetraethylammonium fluoride. The interaction of the nitro-group with fluoride
James H. Clark Jack M. Miller and Kwok-Hung So
pg 941; DOI:
10.1039/P19780000941
PDF
Alkyl di-t-butylphosphinites. Exceptionally halogenophilic phosphinites in Arbuzov reactions
Otto Dahl
pg 947; DOI:
10.1039/P19780000947
PDF
General synthesis of symmetrical and unsymmetrical organic sulphides under non-basic reaction conditions
A. Johan H. Labuschagne Johan S. Malherbe Cornelius J. Meyer and David F. Schneider
pg 955; DOI:
10.1039/P19780000955
PDF
Carbon-13 nuclear magnetic resonance assignments and biosynthesis of versicolorin A in Aspergillus parasiticus
Charles P. Gorst-Allman Pieter S. Steyn Philippus L. Wessels and De Buys Scott
pg 961; DOI:
10.1039/P19780000961
PDF
Fluorination with xenon difluoride. Part 18. Reactivity of diphenyl sulphide and substituted thiochromanones
Marko Zupan and Barbara Zajc
pg 965; DOI:
10.1039/P19780000965
PDF
S-alkylation of sulphides by an activated carbohydrate epimine under acidic catalysis: formation of -acetamido-sulphides. Part 3. Further investigation of the reaction with -(alkylthio)alkanethiols
Brian Bannister
pg 967; DOI:
10.1039/P19780000967
PDF
Nitrosation and nitrosylation of haemoproteins and related compounds. Part 1. Porphyrins and metalloporphyrins
Raymond Bonnett Antonios A. Charalambides and Ronald A. Martin
pg 974; DOI:
10.1039/P19780000974
PDF
Synthesis of 9,11-epoxy-9a-homoprostaglandin analogues
Teunis A. Eggelte Henk de Koning and Henderikus O. Huisman
pg 980; DOI:
10.1039/P19780000980
PDF
Overcrowded molecules. Part 15. Some reactions of (E,E)-, (E,Z)-, and (Z,Z)-2,5-dibenzylidene-3,4-diphenylcyclopentenones and 2,5-dibenzylidene-1,3,5-triphenylcyclopenten-1-ols
Harry G. Heller and Richard D. Piggott
pg 989; DOI:
10.1039/P19780000989
PDF
Diterpenoids of Leonotis Species. Part 5. Leonitin, a 9,13-epoxylabdane from L. leonitis R. Br.
Garth A. Eagle Errol R. Kaplan Krishna Naidu and Douglas E. A. Rivett
pg 994; DOI:
10.1039/P19780000994
PDF
Addition of iodine(I) azide to 3-t-butylcyclohexene and 3-methoxycyclohexene
Richard C. Cambie Peter S. Rutledge Truis Smith-Palmer and Paul D. Woodgate
pg 997; DOI:
10.1039/P19780000997
PDF
Ethyl amidinoacetates in the synthesis of pyrazines
William F. Keir Alexander H. MacLennan and Hamish C. S. Wood
pg 1002; DOI:
10.1039/P19780001002
PDF
Reactions of 2,1,3-benzoselenadiazole and 2,1,3-benzothiadiazole with benzyne and dimethyl acetylenedicarboxylate
Colin D. Campbell Charles W. Rees Martin R. Bryce Michael D. Cooke Peter Hanson and John M. Vernon
pg 1006; DOI:
10.1039/P19780001006
PDF
Formation of ketones from steroidal thioacetals: some sulphur containing steroids
P. Rodney Heaton John M. Midgley and W. Basil Whalley
pg 1011; DOI:
10.1039/P19780001011
PDF
The chemistry of tricarbonyliron complexes of precalciferol2 and tachysterol2
Anthony G. M. Barrett Derek H. R. Barton and Graham Johnson
pg 1014; DOI:
10.1039/P19780001014
PDF
Synthesis of -imino-sulphones. Reaction of the -imino-sulphones with carbon disulphide
Motomu Muraoka Tatsuo Yamamoto Takashi Ebisawa Wataru Kobayashi and Tatsuo Takeshima
pg 1017; DOI:
10.1039/P19780001017
PDF
The preparation and properties of a series of 1,2,5-triazapentadienium salts
Hamish McNab
pg 1023; DOI:
10.1039/P19780001023
PDF
Photochemical and thermal reactions of heterocycles. Part 2. Photolysis of 2,3-diphenylnaphthoquinone 2,3-epoxide: trapping of a cyclic carbonyl ylide and photoisomerisation
Hiroshi Kato Hiroshi Tezuka Kei Yamaguchi Keiko Nowada and Yasuko Nakamura
pg 1029; DOI:
10.1039/P19780001029
PDF
Synthesis of tertiary acyloins using acyl anions formed from 1,3-dithians. Total synthesis of ()-(2E)-1,7-dihydroxy-3,7,11-trimethyl-dodeca-2,10-dien-6-one
Lino Colombo Cesare Gennari Carlo Scolastico and M. Grazia Beretta
pg 1036; DOI:
10.1039/P19780001036
PDF
Total syntheses of the methyl ether ester derivatives of the coccid anthraquinones laccaic acid D and kermesic acid
Guy Roberge and Paul Brassard
pg 1041; DOI:
10.1039/P19780001041
PDF
Reduction of sulphur dioxide with thiols. Synthesis of dialkyl trisulphides
Fuminori Akiyama
pg 1046; DOI:
10.1039/P19780001046
PDF
o-Quinonoid compounds. Part 14. 1,5-Acyl shifts in substituted indenes: migratory aptitudes from racemisation rates
Douglas J. Field David W. Jones and Geoffrey Kneen
pg 1050; DOI:
10.1039/P19780001050
PDF
Water-insoluble papain conjugates of hydrous titanium(IV) oxide and of surface-coating materials modified to contain hydrous titanium(IV) oxide
John F. Kennedy and Victor W. Pike
pg 1058; DOI:
10.1039/P19780001058
PDF
Acyl nitroxides. Part I. Synthesis and isolation
Paul F. Alewood S. Altaf Hussain Terence C. Jenkins M. John Perkins Ashutosh H. Sharma Nancy P. Y. Siew and Peter Ward
pg 1066; DOI:
10.1039/P19780001066
PDF
Nitration of aromatic hydrocarbons and ipso-nitrosodemetallation of arylmetal compounds in sodium nitrite–trifluoroacetic acid
Sakae Uemura Akio Toshimitsu and Masaya Okano
pg 1076; DOI:
10.1039/P19780001076
PDF
Teuflidin, a norclerodane diterpenoid from Teucrium flavum
Giuseppe Savona Maria P. Paternostro Franco Piozzi James R. Hanson Peter B. Hitchcock and Sunday A. Thomas
pg 1080; DOI:
10.1039/P19780001080
PDF
Naphthoquinone colouring matters. Part 1. Synthesis and electronic absorption spectra of 1,4-naphthoquinone derivatives with electron-donating groups in the quinonoid ring
Kwong-Yung Chu and John Griffiths
pg 1083; DOI:
10.1039/P19780001083
PDF
Convenient preparations of di-t-butyl and methyl t-butyl iminodicarboxylates. The use of methyl t-butyl iminodicarboxylate potassium salt as a modified Gabriel reagent
Christopher T. Clarke John D. Elliott and John H. Jones
pg 1088; DOI:
10.1039/P19780001088
PDF
Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 9. New reagents for amination of the ethylenic linkage
Derek H. R. Barton Michael R. Britten-Kelly and Daneel Ferreira
pg 1090; DOI:
10.1039/P19780001090
PDF

Issue 10


Contents pages

pg P021; DOI:
10.1039/P197800FP021
PDF
Synthesis of ubiquinones. Elongation of the heptaprenyl side-chain in ubiquinone-7
Shinji Terao Kaneyoshi Kato Mitsuru Shiraishi and Hiroshi Morimoto
pg 1101; DOI:
10.1039/P19780001101
PDF
Crystal and molecular structure of O-methylbenzoin methylmercurio-(p-tolylsulphonyl)hydrazone
Alessandro Medici Goffredo Rosini Elisabetta Foresti Serantoni and Lodovico Riva di Sanseverino
pg 1110; DOI:
10.1039/P19780001110
PDF
Reaction of benzoyl(phenyl)acetaldehyde with N-phenylhydroxylamine: a re-examination
Francesco De Sarlo and Giovanni Renzi
pg 1113; DOI:
10.1039/P19780001113
PDF
The synthesis, reactions, and spectra of 1-acetoxy-, 1-hydroxy-, and 1-methoxy-indoles
R. Morrin Acheson Paul G. Hunt David M. Littlewood Barry A. Murrer and Howard E. Rosenberg
pg 1117; DOI:
10.1039/P19780001117
PDF
Preparation of ring-fused pyridazines by reduction of 3,3-dinitro-4,4-bipyridyl and 3,3-dinitro-4,4-biquinolyl
Santhi Kanoktanaporn and J. A. Hugh MacBride
pg 1126; DOI:
10.1039/P19780001126
PDF
Acid-catalysed backbone rearrangement involving the CD ring junction in normal steroid series
Mario Anastasia Ada Manzocchi Soave and Antonio Scala
pg 1131; DOI:
10.1039/P19780001131
PDF
Pentatomic heteroaromatic cations. Part 10. A new route for the reduction of the functional group of carboxylic acids, acid chlorides, anhydrides, esters, nitriles, trihalogenomethyl compounds, aldehydes, and ketones to methyl or methylene groups
Iacopo Degani and Rita Fochi
pg 1133; DOI:
10.1039/P19780001133
PDF
Reactions of 3-alkoxy- and 3-alkylthio-benzo[b]thiophen 1,1-dioxides with morpholine, piperidine, and pyrrolidine
Katherine Buggle Patrick McManus and Daniel O'Sullivan
pg 1136; DOI:
10.1039/P19780001136
PDF
cine-Substitution in the thiophen series. Mechanism of the reaction of 3,4-dinitrothophen with sodium arenethiolates in methanol
Marino Novi Giuseppe Guanti Fernando Sancassan and Carlo Dell'Erba
pg 1140; DOI:
10.1039/P19780001140
PDF
Synthesis of 3-acylfurans from 1,3-dicarbonyl compounds and aliphatic nitro-olefins
Tetsuji Yanami Annie Ballatore Masaaki Miyashita Michiharu Kato and Akira Yoshikoshi
pg 1144; DOI:
10.1039/P19780001144
PDF
Syntheses of lignans from 2,3-diarolybutanes
Tesfaye Biftu Braja G. Hazra Robert Stevenson and John R. Williams
pg 1147; DOI:
10.1039/P19780001147
PDF
Spin-lattice relaxation, nuclear Overhauser enhancements, and long range coupling in chlorophylls and metalloporphyrins
Jeremy K. M. Sanders John C. Waterton and Iain S. Denniss
pg 1150; DOI:
10.1039/P19780001150
PDF
Identification by mass spectrometry of N?-formyl-lysine residues in a peptide from bee venom
Shawn Doonan Andrew J. Garman Jennifer M. Hanson Alexander G. Loudon and Charles A. Vernon
pg 1157; DOI:
10.1039/P19780001157
PDF
Ene reactions of allenes. Part 5. Regio- and stereo-selective ene reactions of a trialkylallene
Chan Boo Lee R. John J. Newman and David R. Taylor
pg 1161; DOI:
10.1039/P19780001161
PDF
Intermediates in the halogenation of some 2-aminothiazoles
Luciano Forlani and Alessandro Medici
pg 1169; DOI:
10.1039/P19780001169
PDF
Photoaddition of maleimide to anisole
Derek Bryce-Smith Andrew Gilbert and Brian Halton
pg 1172; DOI:
10.1039/P19780001172
PDF
Total synthesis of prostaglandin-F2 through homoconjugate addition of an organocuprate reagent to a tricyclo[3.2.0.02,7]heptanone
Thomas V. Lee Stanley M. Roberts Michael J. Dimsdale Roger F. Newton D. Kenneth Rainey and Colin F. Webb
pg 1176; DOI:
10.1039/P19780001176
PDF
Preparation and some reactions of 3-endo-substituted tricyclo-[3.2.0.02,7]heptan-6-ones
Thomas V. Lee Stanley M. Roberts and Roger F. Newton
pg 1179; DOI:
10.1039/P19780001179
PDF
Factors governing the ratio of isomeric oxabicyclo[3.2.1]octanones formed on Baeyer–Villiger oxidation of some 5-endo,7-anti-disubstituted bicyclo[2.2.1]heptan-2-ones
Zdzislaw Grudzinski Stanley M. Roberts Colin Howard and Roger F. Newton
pg 1182; DOI:
10.1039/P19780001182
PDF
Prodelphinidin polymers: definition of structural units
Lai Yeap Foo and Lawrence J. Porter
pg 1186; DOI:
10.1039/P19780001186
PDF
Polyene acids. Part 11. Preparation of -tritiated (or deuteriated) conjugated enoic and dienoic acids and their examination by triton magnetic resonance spectroscopy
John A. Elvidge John R. Jones Ramachandra B. Mane and Manouchehr Saljoughian
pg 1191; DOI:
10.1039/P19780001191
PDF
Colour and constitution of the nitro- and dinitro-p-phenylenediamines and their N-methyl derivatives
Kwong-Yung Chu and John Griffiths
pg 1194; DOI:
10.1039/P19780001194
PDF
Competitive cyclisation of singlet and triplet nitrenes. Part 6. The cyclisation of 2-azidophenyl thienyl sulphides
John M. Lindley Otto Meth-Cohn and Hans Suschitzky
pg 1198; DOI:
10.1039/P19780001198
PDF
Polyhalogenonitrobenzenes and derived compounds. Part 1. Reactions of 1,2,3,4-tetrachloro-5,6-dinitrobenzene with amines
Alan Heaton and Michael Hunt
pg 1204; DOI:
10.1039/P19780001204
PDF
Dithiols. Part 29. Syntheses of cis- and trans-2-phenyliminoperhydro-1,3-benzodithiole
Richard C. Forster and Leonard N. Owen
pg 1208; DOI:
10.1039/P19780001208
PDF
Intramolecular nitrene insertions into aromatic and heteroaromatic systems. Part 4. Insertions using triphenylmethanes, unactivated or bearing electron-donating groups
Robert N. Carde Gurnos Jones William H. McKinley and Cynthia Price
pg 1211; DOI:
10.1039/P19780001211
PDF
Regio- and stereo-specificity of cycloaddition reactions of sulphines with diphenylnitrilimine
Bianca F. Bonini Gaetano Maccagnani Germana Mazzanti Lambertus Thijs Gauke E. Veenstra and Binne Zwanenburg
pg 1218; DOI:
10.1039/P19780001218
PDF
Electrophilic fluorination of diazoketones
Jacques Leroy and Claude Wakselman
pg 1224; DOI:
10.1039/P19780001224
PDF
Vinyl carbanions. Part 3. The reaction of -diphenylacrylonitrile derivatives with butyl-lithium
Uri Melamed and Ben A. Feit
pg 1228; DOI:
10.1039/P19780001228
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Vinyl carbanions. Part 4. Use of vinyl carbanions derived from -diphenylacrylonitrile as nucleophiles
Uri Melamed and Ben A. Feit
pg 1232; DOI:
10.1039/P19780001232
PDF
Methods of distinguishing between cyano-stabilised imino- and methylene-phosphoranes. Crystal structures of adducts from triphenylphosphine and tetracyanoethylene (a heptacyanocyclopentenyliminophosphorane) and from triphenylphosphine and dicyanoacetylene (a hexacyanohexa-1,6-dienediphosphorane)
Peter J. Butterfield John C. Tebby and Trevor J. King
pg 1237; DOI:
10.1039/P19780001237
PDF
Chemistry of the compositae. Part 38. Structure and absolute configuration of gallicin, a new germacranolide from Artemisia
Antonio G. González Jaime Bermejo Horacio Mansilla Antonio Galindo Juan M. Amaro and Guillermo M. Massanet
pg 1243; DOI:
10.1039/P19780001243
PDF
Thermal decomposition of sulphenyl carboxylates
Peter A. Bell Donald R. Hogg and Alexander Robertson
pg 1246; DOI:
10.1039/P19780001246
PDF
Sporidesmins. Part 16. The structure of chetomin, a toxic metabolite of Chaetomium cochliodes, by nitrogen-15 and carbon-13 nuclear magnetic resonance spectroscopy
D. Brewer A. G. McInnes D. G. Smith A. Taylor J. A. Walter H. R. Loosli and Z. L. Kis
pg 1248; DOI:
10.1039/P19780001248
PDF
Totally synthetic steroid heterocycles. Part 2. Stereochemistry of hydride reduction of 16-oxa- and 16-thia-8,14-didehydro-D-homoestrone 3-methyl ether and related compounds
Tadao Terasawa and Toshihiko Okada
pg 1252; DOI:
10.1039/P19780001252
PDF
Totally synthetic steroid heterocycles. Part 3. Stereochemical course of oxidation of sulphur in 16-thia-8,14-didehydro-D-homoestrone 3-methyl ether and its derivatives
Tadao Terasawa and Toshihiko Okada
pg 1254; DOI:
10.1039/P19780001254
PDF
Stereoselective total syntheses of the ()-di-O-methyl ethers of agatharesinol, sesquirin-A, and hinokiresinol, and of ()-tri-O-methylsequirin-E, characteristic norlignans of coniferae
Angel Paez Beracierta and Donald A. Whiting
pg 1257; DOI:
10.1039/P19780001257
PDF
The synthesis of nucleosides derived from 5-ethynyluracil and 5-ethynylcytosine
Philip J. Barr A. Stanley Jones Pawe Serafinowski and Richard T. Walker
pg 1263; DOI:
10.1039/P19780001263
PDF
Absolute configuration of the (+)-calamenenes: crystal structure of 7-hydroxycalamenene
Kevin D. Croft Emilio L. Ghisalberti Charles H. Hocart Phillip R. Jefferies Colin L. Raston and Allan H. White
pg 1267; DOI:
10.1039/P19780001267
PDF
18-Hydroxyballonigrin, a new diterpenoid from Ballota acetobulosa
Giuseppe Savona Franco Piozzi James R. Hanson and Michael Siverns
pg 1271; DOI:
10.1039/P19780001271
PDF

Issue 11


Contents pages

pg P025; DOI:
10.1039/P197800FP025
PDF
Alkoxy- and halogeno-selenocyanation of olefins with copper(II) chloride or bromide and potassium selenocyanate
Akio Toshimitsu Yoshihisa Kozawa Sakae Uemura and Masaya Okano
pg 1273; DOI:
10.1039/P19780001273
PDF
Stereochemistry of the bromination of acetylenes with bromine and copper(II) bromide
Sakae Uemura Hajime Okazaki and Masaya Okano
pg 1278; DOI:
10.1039/P19780001278
PDF
Synthesis of 21-hydroxycholesterol and 25-hydroxycholesterol from 3-hydroxyandrost-5-en-17-one. A method for the stereospecific construction of sterol side-chains
Jerzy Wicha and Karol Bal
pg 1282; DOI:
10.1039/P19780001282
PDF
Carbohydrate structures of three new saponins from the root bark of Hovenia dulcis(Rhamnaceae)
Osamu Inoue Tadahiro Takeda and Yukio Ogihara
pg 1289; DOI:
10.1039/P19780001289
PDF
Intramolecular cycloaddition reactions of mono- and di-hydroxypyrimidines
Lyn B. Davies Osman A. Leci Peter G. Sammes and Robert A. Watt
pg 1293; DOI:
10.1039/P19780001293
PDF
Polyaza-azulenes. Part 1. Synthesis and reactions of some 2,3,3a,6-tetrahydropyrazolo[3,4-d][1,2]diazepines
Jonathan R. Frost and Jacques Streith
pg 1297; DOI:
10.1039/P19780001297
PDF
-Tricarbonyl compounds. Part 1. Synthesis of the antibiotics uliginosin A, dihydrouliginosin B, and analogues thereof
Thomas Meikle and Roger Stevens
pg 1303; DOI:
10.1039/P19780001303
PDF
The absolute configuration of (+)-isocamphenilanic acid by X-ray analysis and of (–)-camphene
John M. Midgley W. Basil Whalley Gerhard Buchbauer Gunter W. Hana Heinrich Koch Paul J. Roberts and George Ferguson
pg 1312; DOI:
10.1039/P19780001312
PDF
1,3-Dipolar cycloaddition reactions of aziridines onto 1,2,3-triphenylcyclopropene
Takane Uchida
pg 1315; DOI:
10.1039/P19780001315
PDF
Biosynthesis of oxyacanthine
Dewan S. Bhakuni Awadhesh N. Singh and Sudha Jain
pg 1318; DOI:
10.1039/P19780001318
PDF
Synthesis and stereochemistry of substituted perhydro-2-thiaindan and 2-thiadecalin 2,2-dioxides
Silvio Fabrissin Silvana Fatutta and Amerigo Risaliti
pg 1321; DOI:
10.1039/P19780001321
PDF
Synthesis of quinquevalent phosphoranes from phosphine oxides
Stephen Antczak and Stuart Trippett
pg 1326; DOI:
10.1039/P19780001326
PDF
Cyclisation of benzylamino-nitriles. Part 4. Rearrangement with cyclisation to a benzyl or phenethyl substituent
David N. Harcourt Norman Taylor and Roger D. Waigh
pg 1330; DOI:
10.1039/P19780001330
PDF
Anodic oxidation of organophosphorus compounds. Part 1. Anodic alkylamination of triphenylphosphine
Hidenobu Ohmori Shiro Nakai and Masaichiro Masui
pg 1333; DOI:
10.1039/P19780001333
PDF
cyclo-(L-Phenylalanyl-L-seryl) as an intermediate in the biosynthesis of gliotoxin
Gordon W. Kirby Graham L. Patrick and David J. Robins
pg 1336; DOI:
10.1039/P19780001336
PDF
Synthesis and reactions of cyclic isoimidium salts
Gerhard V. Boyd and René L. Monteil
pg 1338; DOI:
10.1039/P19780001338
PDF
The chemistry of N-substituted 3-amino-1H-2-benzopyran-1-ones and 5-amino-2,3-dihydrofuran-2-ones. Ene-type reactions involving transfer of acyl groups. X-Ray crystal structure of cis-3,4-dihydro-4-morpholinocarbonyl-3-p-nitrophenyl-1H-2-benzopyran-1-one
Gerhard V. Boyd René L. Monteil Peter F. Lindley and Mudhafar M. Mahmoud
pg 1351; DOI:
10.1039/P19780001351
PDF
Isoimidium salts derived from diphenylmethylenesuccinic acid and their conjugate bases. Ene-type reactions involving transfer of acyl groups
Ahmet E. Baydar and Gerhard V. Boyd
pg 1360; DOI:
10.1039/P19780001360
PDF
Studies related to penicillins. Part 18. Epimerisations of benzylpenicillin sulphones
Chandra M. Pant and Richard J. Stoodley
pg 1366; DOI:
10.1039/P19780001366
PDF
The chemistry of terpenes. Part 25. A synthesis of car-2-, car-3-, and car-3(10)-ene (-carene)
Wesley Cocker Niall W. A. Geraghty and David H. Grayson
pg 1370; DOI:
10.1039/P19780001370
PDF
The reaction between 4-methoxy-2,6-dimethylpyrylium perchlorate and amines. Isolation of both 4-iminiopyran salts and pyridinium salts in the reaction with primary amines
Michael P. Sammes and Ka Leung Yip
pg 1373; DOI:
10.1039/P19780001373
PDF
The reaction of arenesulphonyl fluorides with anhydrous aluminium chloride
Timothy Norris
pg 1378; DOI:
10.1039/P19780001378
PDF
Purines, pyrimidines, and imidazoles. Part 49. Adenine and imidazole nucleosides of D-mannofuranose
Grahame Mackenzie and Gordon Shaw
pg 1381; DOI:
10.1039/P19780001381
PDF
Conformational behaviour of medium-sized rings. Part 4. Heterocyclic analogues of 7,8,13,14-tetrahydrobenzo[6,7]cyclonona[1,2,3-de]naphthalene and 7,8,15,16-tetrahydrocyclodeca[1,2,3-de:6,7,8-de]dinaphthalene
David J. Brickwood W. David Ollis and J. Fraser Stoddart
pg 1385; DOI:
10.1039/P19780001385
PDF
Conformational behaviour of medium-sized rings. Part 5. Transannular reactions of (16Z)-8,9-dihydro-8-methyl-7H-dinaphth-[1,8-cd:1,8-hi]azacycloundecine and (12Z)-6,7-dihydro-6-methyl-5H-dibenz[c,g]azonine. Two examples of reverse Hofmann eliminations
David J. Brickwood Afaf M. Hassan W. David Ollis Julia Stephanidou Stephanatou and J. Fraser Stoddart
pg 1393; DOI:
10.1039/P19780001393
PDF
Conformational behaviour of medium-sized rings. Part 6. 5,6,11,12,17,18-Hexahydrotribenzo[a,e,i]cyclododecene and its 2,3,8,9,14,15- and 1,4,7,10,13,16-hexamethyl derivatives. 2,3,8,9- and 1,4,7,10-Tetramethyl-5,6,11,12-tetrahydrodibenzo[a,e]cyclo-octene
David J. Brickwood W. David Ollis Julia Stephanidou Stephanatou and J. Fraser Stoddart
pg 1398; DOI:
10.1039/P19780001398
PDF
Conformational behaviour of medium-sized rings. Part 7. 5,6,7,12-Tetrahydrodibenzo[a,d]cyclo-octene
Farouk Eltayeb Elhadi W. David Ollis and J. Fraser Stoddart
pg 1415; DOI:
10.1039/P19780001415
PDF
Conformational behaviour of medium-sized rings. Part 8. 6H,12H,18H-Tribenzo[b,f,j][1,5,9]trithiacyclododecin and its 5,5,11,11,17,17-hexaoxide
W. David Ollis Julia Stephanidou Stephanatou J. Fraser Stoddart and Michael Nóagrádi
pg 1421; DOI:
10.1039/P19780001421
PDF
Addition reactions of acetylenic esters with monosubstituted thioureas
Libero Italo Giannola Salvatore Palazzo Pasquale Agozzino Liliana Lamartina and Leopoldo Ceraulo
pg 1428; DOI:
10.1039/P19780001428
PDF
Photochemical induced cistrans-isomerization of substituted -(4H-3,1-benzothiazin-4-ylidene) ketones and esters
Christian Lohse Carl Th. Pedersen Max Ebel and Raymond Callendret
pg 1432; DOI:
10.1039/P19780001432
PDF
Carbon-13 and proton magnetic resonance spectra of 2,2-dialkyl-5,5-dimethylcyclohexane-1,3-diones (2,2-dialkyldimedones)
Jaswant R. Mahajan
pg 1434; DOI:
10.1039/P19780001434
PDF
Further syntheses of quinquevalent spirophosphoranes by using N-chlorodi-isopropylamine
Santokh Singh Mary Swindles Stuart Trippett and Robin E. L. Waddling
pg 1438; DOI:
10.1039/P19780001438
PDF
On the alkylation of multisite aromatic heterocycles. Part 2. Formation and thermal decomposition of 4-alkyl-5-alkylimino-1,2,3,4-thiatriazolines
Nils Henrik Toubro and Arne Holm
pg 1440; DOI:
10.1039/P19780001440
PDF
Photolytic formation of nitrile sulphides from five-membered heterocyclic compounds
Arne Holm and Nils Henrik Toubro
pg 1445; DOI:
10.1039/P19780001445
PDF
Synthesis of some 1-oxadethiaceph-3-ems
Clive L. Branch John H. C. Nayler and Michael J. Pearson
pg 1450; DOI:
10.1039/P19780001450
PDF
Diazepines. Part 23. The formation and structure of 1,5-diaza- and 5-aza-1-oxa-pentadienium salts and their use in the preparation of 2,3-dihydro-1,4-diazepinium salts
Douglas Lloyd Hamish McNab and Donald R. Marshall
pg 1453; DOI:
10.1039/P19780001453
PDF

Issue 12


Contents pages

pg P029; DOI:
10.1039/P197800FP029
PDF
The reactions of 5-allyl-1,1-ethylenedioxy-5,9-dimethyl-trans-decalin-6-one, a potential intermediate in the synthesis of friedolabdanes
Angel Ardon-Jimenez and Thomas G. Halsall
pg 1461; DOI:
10.1039/P19780001461
PDF
Reactions with arenesulphonyl azides of some indoles with oxygen- and nitrogen-containing substituents
A. Sydney Bailey Christopher M. Birch David Illingworth and Janet C. Willmott
pg 1471; DOI:
10.1039/P19780001471
PDF
Sporidesmins. Part 17. Isolation of sporidesmin H and sporidesmin J
R. Rahman S. Safe and A. Taylor
pg 1476; DOI:
10.1039/P19780001476
PDF
Indane 3a,4-oxide: formation by isomerisation of indane 3a,7a-oxide and confirmation of structure by an alternative synthesis
Stephen G. Davies and Gordon H. Whitham
pg 1479; DOI:
10.1039/P19780001479
PDF
Cleavage of vicinal diols by iodine triacetate and iodine(I) acetate
Richard C. Cambie David Chambers Peter S. Rutledge and Paul D. Woodgate
pg 1483; DOI:
10.1039/P19780001483
PDF
Natural acetylenes. Part 53. A route to C5, C6, and C7cis- and trans-alk-3-en-1-ynes via their trimethylsilyl derivatives
Iain W. Farrell Milton T. W. Hearn and Viktor Thaller
pg 1485; DOI:
10.1039/P19780001485
PDF
Natural acetylenes. Part 54. Polyacetylenes from fungal cultures of some tricholomataceae and corticiaceae species
Mahtabuddin Ahmed John W. Keeping Theodore A. Macrides and Viktor Thaller
pg 1487; DOI:
10.1039/P19780001487
PDF
3,7-Bis(hydroxymethyl)-1-benzoxepin-5(2H)-one, a novel oxygen heterocyclic metabolite from cultures of the fungus Marasmiellus ramealis(Bull. ex Fr.) singer
John K. Holroyde Alex F. Orr and Viktor Thaller
pg 1490; DOI:
10.1039/P19780001490
PDF
The synthesis of some compounds related to muscarine
Kenneth Bowden and Brian H. Warrington
pg 1493; DOI:
10.1039/P19780001493
PDF
Synthetic studies on the heterocyclic nucleus of the cytochalasans
Christopher Owens and Ralph A. Raphael
pg 1504; DOI:
10.1039/P19780001504
PDF
The acetoxyfulvene synthesis of prostaglandins. Part 1. Synthesis of the corey aldehyde
Edward D. Brown Richard Clarkson Timothy J. Leeney and Graham E. Robinson
pg 1507; DOI:
10.1039/P19780001507
PDF
Carotenoids and related compounds. Part 35. Synthesis of ()-azafrin methyl ester and other -glycols
Muhammad Akhtar A. Erol Faruk C. John Harris Gerard P. Moss Stephen W. Russell and Basil C. L. Weedon
pg 1511; DOI:
10.1039/P19780001511
PDF
Studies of oxazolobenzodiazepines. Part 7. Synthesis of 3-methyloxazolo[3,2-d][1,4]benzodiazepines and configurational studies of their ketimine intermediates
Ryuji Tachikawa Tetsuo Miyadera Chihiro Tamura Atsusuke Terada Shunji Naruto and Eiichi Nagamatsu
pg 1524; DOI:
10.1039/P19780001524
PDF
Hydroxy-steroids. Part 20. Distinction between 19-norergosta-5,7,9-trien-3-ol (dihydroneoergosterol) and its 3-epimer
Gerald Felsky Peter M. Fredericks and G. Denis Meakins
pg 1529; DOI:
10.1039/P19780001529
PDF
Hydroxy-steroids. Part 21. The preparation and proton nuclear magnetic resonance spectra of 19-norergosta-3,5,7,9,22-pentaene and -3,5,7,9-tetraene, 7-methoxy-1,2-dihydronaphthalene, and deuteriated derivatives
T. Geoffrey C. Bird Gerald Felsky and G. Denis Meakins
pg 1533; DOI:
10.1039/P19780001533
PDF
Steroidal analogues of unnatural configuration. Part 13. Synthesis and ring B reactions of 4,4,9-trimethyl-9,10-estr-5-ene
James R. Bull Jan Floor and Albert Tuinman
pg 1537; DOI:
10.1039/P19780001537
PDF
Studies on the conformational transitions of rat skin collagen using a spin-label probe
Milton T. W. Hearn Michael L. Jenkinson Donald B. Myers and Barry M. Peake
pg 1542; DOI:
10.1039/P19780001542
PDF
Benzoyl-substituted thiirans and oxathioles. The synthesis and properties of 2-benzoyl-5-phenyl-1,3-oxathiole
Ulla Jacobsson Kempe Tomas Kempe and Torbjörn Norin
pg 1547; DOI:
10.1039/P19780001547
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Photochemistry of 7-syn-isobutylnorborn-2-en-2-yl methyl ketone. Intramolecular hydrogen abstraction in an ,-unsaturated ketone with geometrically equivalent - and -carbon atoms
Brian Byrne Charles A. Wilson II Steven Wolff and William C. Agosta
pg 1550; DOI:
10.1039/P19780001550
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Structural elucidation of a new group of secostictane triterpenoids
Eng Meng Goh Alistair L. Wilkins and Patrick T. Holland
pg 1560; DOI:
10.1039/P19780001560
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The oxyallyl cation in synthesis: preparation of analogues of cocaine
Antony P. Cowling and John Mann
pg 1564; DOI:
10.1039/P19780001564
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Cycloadditions to conjugated diallenes
Charles Boan and Lars Skattebøl
pg 1568; DOI:
10.1039/P19780001568
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Antitumour plants. Part 6. Novel modified germacranolides and other constituents of Eremanthus elaeagnus Schultz-bip (compositae)
Philip W. Le Quesne Steven B. Levery Mary D. Menachery Thomas F. Brennan and Robert F. Raffauf
pg 1572; DOI:
10.1039/P19780001572
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The reactions of aryloxysulphoxonium salts with amines and other nucleophiles
G. Roger Chalkley David J. Snodin Graham Stevens and Mark C. Whiting
pg 1580; DOI:
10.1039/P19780001580
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Synthesis of some 2-phenylpyrrole derivatives
John W. ApSimon David G. Durham and Alun H. Rees
pg 1588; DOI:
10.1039/P19780001588
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Alkylated steroids. Part 2. 16,17-Dimethylpregnanes functionalised in ring C
James Cairns (the late) Colin L. Hewett Robert T. Logan George McGarry Robert G. Roy Donald F. M. Stevenson and Gilbert F. Woods
pg 1594; DOI:
10.1039/P19780001594
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Further polyacetylenes from Polyporus anthracophilus: specific incorporation of [1-14C]matricaria esters into polyacetylenic metabolites of this fungus
David G. Davies Philip Hodge Paul Yates and Malcolm J. Wright
pg 1602; DOI:
10.1039/P19780001602
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Rearrangement of epoxides. Part 2. The preparation and rearrangement of some epoxides of 2,2-dimethylbicyclo[4.3.0]non-1(9)-enes carrying substituents at C(3) and C(6)
Thomas G. Halsall Philip J. McHale and Antonio Morales Mendez
pg 1606; DOI:
10.1039/P19780001606
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Steroidal heterocycles: 2-thiocyanatoandrosteno-[3,2-d]pyrimidines and -[17,16-d]pyrimidines
Joginder S. Bajwa and Peter J. Sykes
pg 1618; DOI:
10.1039/P19780001618
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The isolation and structures of the fungal metabolites lapidosin and diversonol
W. Brian Turner
pg 1621; DOI:
10.1039/P19780001621
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Evidence of a dissociative SN1(P) mechanism of phosphoryl transfer by rabbit muscle pyruvate kinase
Gordon Lowe and Brian S. Sproat
pg 1622; DOI:
10.1039/P19780001622
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Rhodium(I)-catalysed dimerisation of terminal acetylenes at ambient temperature and pressure
Laurence Carlton and Gordon Read
pg 1631; DOI:
10.1039/P19780001631
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Oxidation and isomerisation of colupulone; the separation and structures of two transformation products
Gareth D. John and Patrick V. R. Shannon
pg 1633; DOI:
10.1039/P19780001633
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Enzymes in organic synthesis. Influence of substrate structure on rates of horse liver alcohol dehydrogenase-catalysed oxidoreductions
Anthony J. Irwin Kar P. Lok Ketz W-C. Huang and J. Bryan Jones
pg 1636; DOI:
10.1039/P19780001636
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On steroids. Part 209. Formation of 6-bromo-5-chloro-5-cholestan-3-ol on addition of bromine chloride to cholesterol
Alexander Kasal
pg 1642; DOI:
10.1039/P19780001642
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Organic synthesis with sulphones. Part 14. Nucleophilic substitution on styryl sulphones; a new route to arylacetaldehydes
Marc Julia Anne Righini and Daniel Uguen
pg 1646; DOI:
10.1039/P19780001646
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Synthesis of unsaturated 5-hydroxy- and 7-oxo-acids by addition of unsaturated carboxylic acid dienolates to carbonyl compounds
Ismael Casinos and Ramón Mestres
pg 1651; DOI:
10.1039/P19780001651
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Analysis of petroporphyrins by chemical ionisation mass spectrometry
George J. Shaw J. Martin E. Quirke and Geoffrey Eglinton
pg 1655; DOI:
10.1039/P19780001655
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Wittig condensation products from nickel meso-formyl-octaethyl-porphyrin and -aetioporphyrin I and some cyclisation reactions
Dennis P. Arnold Richard Gaete-Holmes Alan W. Johnson Andrew R. P. Smith and Geoffrey A. Williams
pg 1660; DOI:
10.1039/P19780001660
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Quadrigemines-A and-B, two minor alkaloids of Hodgkinsonia frutescens F. Muell
Keith P. Parry and George F. Smith
pg 1671; DOI:
10.1039/P19780001671
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Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 9. New reagents for amination of the ethylenic linkage
Derek H. R. Barton Michael R. Britten-Kelly and Daneel Ferreira
pg 1682; DOI:
10.1039/P19780001682
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